Answer :
Explanation:
When iodine heptafluoride reacts rapidly with water to give a mixture of periodic acid and hydrofluoric acid. Reaction equation for the same is as follows.
[tex]IF_{7} + 6H_{2}O \rightarrow H_{5}IO_{6} + 7HF[/tex]
As it is given that there are [tex]3.72 \times 10^{-2}[/tex] moles of iodine heptafluoride are present. Molar mass of [tex]IF_{7}[/tex] is 259.9 g/mol. Molar mass of [tex]HIO_{4}[/tex] is 227.94 g/mol and molar mass of HF is 20.01 g/mol.
Now, according to the reaction equation [tex]3.72 \times 10^{-2}[/tex] M [tex]IF_{7}[/tex] gives [tex]3.72 \times 10^{-2}[/tex] M [tex]H_{5}IO_{6}[/tex].
Also, the volume is given as 795 ml or 0.795 L (as 1 mL = 0.001 L).
Hence, calculate the concentration of [tex]H_{5}IO_{6}[/tex] into the solution as follows.
Concentration = [tex]\frac{\text{no. of moles}}{volume}[/tex]
= [tex]\frac{3.72 \times 10^{-2}}{0.795 L}[/tex]
= [tex]4.7 \times 10^{-2}[/tex] mol/L
or, = 0.047 M
Now, as 1 mol of [tex]IF_{7}[/tex] produces 7 mol HF. So, [tex]7 \times 3.72 \times 10^{-2} = 26.04 \times 10^{-2}[/tex] M HF.
Therefore, concentration of HF will be calculated as follows.
Concentration of HF = [tex]\frac{0.2604}{0.795}[/tex]
= 0.33 M
Thus, we can conclude that concentration of periodic acid is 0.047 M and concentration of hydrofluoric acid is 0.33 M.