Answer :
Answer:
a. NaH₂PO₄(aq) + H⁺(aq) → H₃PO₄(aq) + Na⁺(aq)
b. H₃PO₄(aq) + OH⁻(aq) → H₂PO₄⁻(aq) + H₂O(l)
Explanation:
A buffer is the mixture of a weak acid and its conjugate base or vice versa.
a. Added acid will react with NaH₂PO₄ (Conjugate base) thus:
NaH₂PO₄(aq) + H⁺(aq) → H₃PO₄(aq) + Na⁺(aq)
When all NaH₂PO₄ reacts, the solution will have just H₃PO₄ and the buffer lose its capacity.
b. In the same way, added base will react with H₃PO₄ (weak acid), thus:
H₃PO₄(aq) + OH⁻(aq) → H₂PO₄⁻(aq) + H₂O(l)
Also, when all H₃PO₄ reacts, the solution will have just H₂PO₄⁻ and the buffer lose its capacity.
I hope it helps!
Answer:
(a) H₃O⁺(aq) + H₂PO₄⁻(aq) ⟶ H₃PO₄(aq) + H₂O(ℓ)
(b) OH⁻(aq) + H₃O⁺(aq) ⟶ 2H₂O(ℓ)
Explanation:
The equation for your buffer equilibrium is:
H₃PO₄(aq) + H₂O(ℓ) ⇌ H₃O⁺(aq)+ H₂PO₄⁻(aq)
(a) Adding H₃O⁺
The hydronium ions react with the basic dihydrogen phosphate ions.
H₃O⁺(aq) + H₂PO₄⁻(aq) ⟶ H₃PO₄(aq) + H₂O(ℓ)
(b) Adding OH⁻
The OH⁻ ions react with the more acidic hydronium ions.
OH⁻(aq) + H₃O⁺(aq) ⟶ 2H₂O(ℓ)