Answer:check explanation and attached file/picture
Explanation:
Alkynes are hydrocarbons and they are very acidic because of hybridization effect(the more acidic the s-character is, the more acidic it is going to be).
The reaction of 1-hexyne with sodium amide in liquid ammonia is a form of deprotonation 'reaction' to form acetylide. Due to the acidic nature of the terminal hydrogen atom, terminal alkynes do form metallic derivatives by the replacement of the terminal hydrogens. The equation of Reaction is given below.
C6H10 + NaNH2( in liquidNH3) ------------> C6H9Na + H-NH2.
The acetylide is a bae and a very good nucleophile.
The reaction is then followed by the addition of 1-bromobutane. This reaction is used for the production of longer chain alkynes. The equation of Reaction is attached in the picture.
Answer:
CH3(CH2)3CCH --> CH3(CH2)3CCCH2(CH2)2CH3 + NaBr
Explanation:
This reaction are used in the elongation of a terminal alkyne chain, it can be in 2 steps:
Step 1:
NaNH2 is in this reaction is used in the deprotonation of 1-hexyne to give acetylide ions( RCC-). The ion is an nucleophile because of the lone pair of electrons.
Step 2:
This acetylide ion is a basic ion (because 1-hexyne is a weak acid). The alky halide (1-bromobutane) dissociates to form a primary cation and Br- ion. This cation then attacks the acetylide ion, reacts to form carbon-carbon bonds as well as add to carbonyl.
Below is an attachment for the chemical reaction.
