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Balance the following skeleton ionic reaction, and calculate E°cell to decide whether the reaction is spontaneous: Ag(s) + Cu2+ (aq) LaTeX: \longrightarrow⟶ Ag+ (aq) + Cu(s) Enter a number so 1, 2, 3 etc E°cell = spontaneous? enter yes or no (MTS 3/3/2019)

Answer :

Answer:

2Ag(s) + Cu^2+(aq) ----------> 2Ag^+(aq) + Cu(s)

Explanation:

Ag(s)/Ag^+ (aq) is the anode as shown while Cu^2+(aq)/Cu^2(s) is the cathode.

E°cell= E°cathode -E°anode= 0.34 -0.80= -0.5V

The cell is not spontaneous as written because E°cell is negative. This implies that the electrodes of the cell must be interchanged to make the cell spontaneous.

The balanced equation and the Ecell is mathematically given as

2Ag(s) + Cu2+ (aq) ⟶ 2Ag+ (aq) + Cu(s)

Ecell = +1.14 V.

What is E°cell to decide whether the reaction is spontaneous?

Question Parameter(s):

Ag(s) + Cu2+ (aq) ------> Ag+ (aq) + Cu(s

Generally, the equation for the Chemical Reaction  is mathematically given as

Ag(s) + Cu2+ (aq) ------> Ag+ (aq) + Cu(s)

Therefore,the Reduction reaction and Oxidation reaction are

Reduction reaction

Cu2+(aq) + 2e ----->> Cu(s)

E = 0.34 V

Oxidation reaction

2Ag(s) --> 2Ag+(aq) + 2e-

E = -0.80 V

In conclusion

2Ag(s) + Cu2+ (aq) ⟶ 2Ag+ (aq) + Cu(s)

Ecell = Ecath - Eano

Ecell = 0.34 - (-0.80)

Ecell = +1.14 V.

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