Calculate the [H+] and pH of a 0.0010 M acetic acid solution. The Ka of acetic acid is 1.76×10−5. Use the method of successive approximations in your calculations.

Answer :

sebassandin

Answer:

[tex][H^+]=0.000123M[/tex]

[tex]pH=3.91[/tex]

Explanation:

Hello,

In this case, dissociation reaction for acetic acid is:

[tex]CH_3COOH\rightleftharpoons CH_3COO^-+H^+[/tex]

For which the equilibrium expression is:

[tex]Ka=\frac{[CH_3COO^-][H^+]}{[CH_3COOH]}[/tex]

Which in terms of the reaction extent [tex]x[/tex] could be written as:

[tex]1.74x10^{-5}=\frac{x*x}{[CH_3COOH]_0-x}=\frac{x*x}{0.0010M-x}[/tex]

Thus, solving by using a solver or quadratic equation we obtain:

[tex]x_1=0.000123M\\\\x_2=-0.000141M[/tex]

And clearly the result is 0.000123M, which also equals the concentration of hydronium ion in solution:

[tex][H^+]=0.000123M[/tex]

Now, the pH is computed as follows:

[tex]pH=-log([H^+])=-log(0.000123)\\\\pH=3.91[/tex]

Best regards.

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