Answer :
Allotrope 1 has the higher melting point because it lacks the covalent bonds between phosphorus atoms that are present in allotrope 2.
The Melting Point Differences Between Allotropes of Solid Phosphorus
Allotropes of solid phosphorus are different forms of the element which differ in their molecular arrangement and structure. Allotrope 1 is a more stable form and has a higher melting point than that of allotrope 2 due to the absence of covalent bonds between the phosphorus atoms in allotrope 1.
The structure of allotrope 1 is an ordered arrangement in which the phosphorus atoms form a three-dimensional lattice. This lattice structure is held together by strong Van der Waals forces, which are electrostatic attractions between the atoms. This structure is more stable than that of allotrope 2 and has a higher melting point due to the increased strength of the interatomic forces.
In contrast, the structure of allotrope 2 is much less ordered, and the phosphorus atoms are held together by covalent bonds. This structure is not as stable as that of allotrope 1 and has a lower melting point. The covalent bonds between the phosphorus atoms are much weaker than the forces in allotrope 1, and consequently the melting point of allotrope 2 is lower.
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